首页 期刊 结构化学 Synthesis, Photo-physical Properties and Cell Imaging of Meso-2,6-dichlorophenyl Boron-dipyrromethene Derivatives 【正文】

Synthesis, Photo-physical Properties and Cell Imaging of Meso-2,6-dichlorophenyl Boron-dipyrromethene Derivatives

作者:陶家宇; 宋文婷; 孙磊; 李铮铮; 付博; 蔡正春; 徐海军 Jiangsu; Co-innovation; Center; of; Efficient; Processing; and; Utilization; of; Forest; Resources; College; of; Chemical; Engineering; Nanjing; Forestry; University; Nanjing210037; China; State; Key; Laboratory; of; Coordination; Chemistry; Nanjing; University; Nanjing210000; China; Jiangsu; Key; Lab; of; Biomass-based; Green; Fuels; and; Chemicals; Nanjing; Forestry; University; Nanjing210037; China
bodipy   properties   cell   imaging   crystal  

摘要:The meso-2,6-dichlorophenyl boron-dipyrromethene(BODIPY) derivative 1 was synthesized and characterized by single-crystal X-ray diffraction analysis, 1 H NMR and Esi-HRMS. Compound 1 crystallizes in monoclinic, space group P21/n with a = 8.717(4), b = 20.938(9), c = 12.402(6) ?, β = 98.660(7)°, V = 2237.7(17) ?3, D3 c = 1.333 Mg/cm, F(000) = 936, μ = 0.319 –mm1, Z = 4, the final R = 0.0537 and wR = 0.1556 for 5064 observed reflections with I > 2ζ(I). Its photophysical properties were investigated by fluorescence and UV-Vis spectrum. 1 shows high fluorescence quantum yield in different solvents and poor solvent effect. In addition, compound 1 has high values of initial decomposition temperature(298 ℃). Moreover, cell imaging experiments showed 1 is promising for further bioimaging applications.

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