摘要:在水热反应条件下成功地合成两个同构的Ln-Co异金属配位聚合物:[Ln4Co(QDA)2(QA)6(OH)4(H2O)4](Ln=Gd1,Lu2;H2QDA=喹啉-2,3-二羧酸,HQA=喹啉-3-羧酸)。这两个配合物通过芳香环之间的π-π堆积作用连接呈现出三维超分子结构框架。另外对其进行了红外光谱(IR)、粉末X-射线衍射(XRD)、热稳定性(TGA)性能表征。
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